Searching for superconductivity in high entropy oxide Ruddlesden–Popper cuprate films

نویسندگان

چکیده

In this work, the high entropy oxide A2CuO4 Ruddlesden-Popper (La0.2Pr0.2Nd0.2Sm0.2Eu0.2)2CuO4 is explored by charge doping with Ce+4 and Sr+2 at concentrations known to induce superconductivity in simple parent compounds, Nd2CuO4 La2CuO4. Electron doped (La0.185Pr0.185Nd0.185Sm0.185Eu0.185Ce0.075)2CuO4 hole (La0.18Pr0.18Nd0.18Sm0.18Eu0.18Sr0.1)2CuO4 are synthesized shown be single crystal, epitaxially strained, highly uniform. Transport measurements demonstrate that all as-grown films insulating regardless of doping. Annealing studies show resistivity can tuned modifying oxygen stoichiometry inducing metallicity but without superconductivity. These results turn connected extended x-ray absorption fine structure (EXAFS) indicating lack cuprates likely originates from a large distortion within Cu-O plane ({\sigma}2>0.015 {\AA}2) due A-site cation size variance, which drives localization carriers. findings describe new opportunities for controlling charge- orbital-mediated functional responses crystal structures, driven balancing variances may exploited functionally important behaviors such as superconductivity, antiferromagnetism, metal-insulator transitions, while opening less understood phase spaces hosting Mott insulators, strange metals, quantum criticality, pseudogaps, ordered density waves.

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ژورنال

عنوان ژورنال: Journal of vacuum science & technology

سال: 2021

ISSN: ['2327-9877', '0734-211X']

DOI: https://doi.org/10.1116/6.0001441